To use the empheq package be sure to use the following line in your preamble.
\usepackage{empheq}
Then in your document you can use:
\begin{subequations}
\begin{empheq}[left=\empheqlbrace]{align}
x &= y + z \\
y &= \sin(\theta)
\end{empheq}
\end{subequations}
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